During dehydration of alcohols to alkenes by heating with concentrated H2SO4

During dehydration of alcohols to alkenes by heating with concentrated H2SO4 the initiation step is

  1. protonation of alcohol molecule
  2. formation of an ester
  3. formation of carbocation
  4. elimination of water

Answer

Dehydration of alcohol to alkene in presence of concentrated H2SO4 involves the –OH group in the alcohol that donates two electrons to H+ from the acid reagent, forming an alkyloxonium ion. The deprotonated acid (the nucleophile) then attacks the hydrogen adjacent to the carbocation and form a double bond.

Thus, the initiation step is protonation of alcohol.

The correct option is A.